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KMID : 0368019830060030355
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Journal of Soonchunhyang University
1983 Volume.6 No. 3 p.355 ~ p.358
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Transfer Hydrogenation of Trans-Dinitrogen Bisdiphenyl Phosphinoethane Molybdenum(0)
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Park Moo-Soon
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Abstract
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The Dinitrogen complex trans-Mo(N2)z(DPPE)z (DPPE=Ph2PCI-15CYI2PPh2) was found to be an excellent catalyst for hydrogen transfer from organic compounds to olefins. Secondary alcohols were found much more effective as hydrogen donors than primary alcohols or hydroaromatic compounds. Although a-olefins were also reduced by secondary alcoholstetrahydrofuran in the presence of trans-Mo(Nz)z(DPPE)?, double bond migration occurred simultaneously. The catalytic activity of related complexes of molybdenum for transfer hydrogenation was investigated.
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